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Characterization of Gas-Phase Organics Using Proton Transfer Reaction Time-of-Flight Mass Spectrometry: Residential Coal Combustion

Authors: Jay G. Slowik; Amelie Bertrand; Brice Temime-Roussel; Dogushan Kilic; Felix Klein; Junji Cao; Imad El Haddad; +9 Authors

Characterization of Gas-Phase Organics Using Proton Transfer Reaction Time-of-Flight Mass Spectrometry: Residential Coal Combustion

Abstract

Residential coal combustion is a significant contributor to particulate urban air pollution in Chinese mega cities and some regions in Europe. While the particulate emission factors and the chemical characteristics of the organic and inorganic aerosol from coal combustion have been extensively studied, the chemical composition and nonmethane organic gas (NMOG) emission factors from residential coal combustion are mostly unknown. We conducted 23 individual burns in a traditional Chinese stove used for heating and cooking using five different coals with Chinese origins, characterizing the NMOG emissions using a proton transfer reaction time-of-flight mass spectrometer. The measured emission factors range from 1.5 to 14.1 g/kgcoal for bituminous coals and are below 0.1 g/kgcoal for anthracite coals. The emission factors from the bituminous coals are mostly influenced by the time until the coal is fully ignited. The emissions from the bituminous coals are dominated by aromatic and oxygenated aromatic compounds with a significant contribution of hydrocarbons. The results of this study can help to improve urban air pollution modeling in China and Eastern Europe and can be used to constrain a coal burning factor in ambient gas phase positive matrix factorization studies.

Countries
France, China (People's Republic of)
Keywords

[ SDU.OCEAN ] Sciences of the Universe [physics]/Ocean, Atmosphere, Technology, China, 550, WOOD COMBUSTION, Environmental Sciences & Ecology, PM2.5, CHINA, Mass Spectrometry, Environmental, CARBON, Engineering, POLLUTION, Reaction Time, Europe, Eastern, EMISSION FACTORS, HOUSEHOLD STOVES, [SDU.OCEAN]Sciences of the Universe [physics]/Ocean, Atmosphere, Air Pollutants, Science & Technology, [SDU.OCEAN] Sciences of the Universe [physics]/Ocean, Atmosphere, ATMOSPHERE, COOKSTOVES, 620, Europe, [ SDE.MCG ] Environmental Sciences/Global Changes, Coal, [CHIM.OTHE] Chemical Sciences/Other, [ CHIM.ANAL ] Chemical Sciences/Analytical chemistry, Protons, HAZE EVENTS, [CHIM.OTHE]Chemical Sciences/Other, Life Sciences & Biomedicine, Environmental Sciences, [ SDE.ES ] Environmental Sciences/Environmental and Society

  • BIP!
    Impact byBIP!
    citations
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    35
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 10%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 10%
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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
35
Top 10%
Top 10%
Top 10%
Green
hybrid