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Industrial & Engineering Chemistry Research
Article . 2020 . Peer-reviewed
License: CC BY
Data sources: Crossref
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Kinetic Characterization of Tar Reforming on Commercial Ni-Catalyst Pellets Used for In Situ Syngas Cleaning in Biomass Gasification: Experiments and Simulations under Process Conditions

Authors: Andrea Di Giuliano; Pier Ugo Foscolo; Andrea Di Carlo; Andrew Steele; Katia Gallucci;

Kinetic Characterization of Tar Reforming on Commercial Ni-Catalyst Pellets Used for In Situ Syngas Cleaning in Biomass Gasification: Experiments and Simulations under Process Conditions

Abstract

Filtering-catalytic candles, filled with an annular packed-bed of commercial Ni-catalyst pellets (∼600 g), were successfully tested for in situ syngas cleaning in a fluidized-bed biomass steam gasifier [Fuel Process. Technol.2019, 191, 44-53, DOI: 10.1016/j.fuproc.2019.03.018]. Those tests enabled the macroscopic evaluation of gasification and gas cleaning as a whole, requiring a more specific assessment of the catalyst performance inside the filter candle. To this end, steam reforming tests of tar key compounds (naphthalene and toluene; thiophene in traces to observe sulfur deactivation) were performed with a laboratory-scale packed-bed reactor containing the same catalyst pellets (<7 g). A lumped kinetics was derived, referred to a pseudocomponent representing tars. This was then validated by simulation of the annular catalytic packed bed inside the filter candle, obtaining numerical results in fair agreement with gasifier outputs. As a result, the lab-scale investigation with a small amount of catalyst provides reliable predictions of tar catalytic reforming in industrial-scale filtering-catalytic candles.

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    11
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 10%
    influence
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    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
11
Top 10%
Average
Top 10%
Green
hybrid