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Capacitive Dark Currents, Hysteresis, and Electrode Polarization in Lead Halide Perovskite Solar Cells

pmid: 26263328
Despite spectacular advances in conversion efficiency of perovskite solar cell many aspects of its operating modes are still poorly understood. Capacitance constitutes a key parameter to explore which mechanisms control particular functioning and undesired effects as current hysteresis. Analyzing capacitive responses allows addressing not only the nature of charge distribution in the device but also the kinetics of the charging processes and how they alter the solar cell current. Two main polarization processes are identified. Dielectric properties of the microscopic dipolar units through the orthorhombic-to-tetragonal phase transition account for the measured intermediate frequency capacitance. Electrode polarization caused by interfacial effects, presumably related to kinetically slow ions piled up in the vicinity of the outer interfaces, consistently explain the reported excess capacitance values at low frequencies. In addition, current-voltage curves and capacitive responses of perovskite-based solar cells are connected. The observed hysteretic effect in the dark current originates from the slow capacitive mechanisms.
- King Abdulaziz University Saudi Arabia
- King Abdulaziz University Saudi Arabia
- James I University Spain
- Jaume I University Spain
- Jaume I University Spain
capacitance, electrode polarization, photovoltaics, lead halide perovskites, hysteresis
capacitance, electrode polarization, photovoltaics, lead halide perovskites, hysteresis
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Data source Views Downloads Repositori Institucional de la Universitat Jaume I 24 0

