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ACS Energy Letters
Article
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ACS Energy Letters
Article . 2019
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ACS Energy Letters
Article . 2018 . Peer-reviewed
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Minimizing Voltage Loss in Wide-Bandgap Perovskites for Tandem Solar Cells

Authors: Claire H. Burgess; Benedito A. L. Raul; Jef Poortmans; Jef Poortmans; Afshin Hadipour; Yinghuan Kuang; Manoj Jaysankar; +7 Authors

Minimizing Voltage Loss in Wide-Bandgap Perovskites for Tandem Solar Cells

Abstract

Perovskites with bandgaps between 1.7 and 1.8 eV are optimal for tandem configurations with crystalline silicon (c-Si) because they facilitate efficient harvest of solar energy. In that respect, achieving a high open-circuit voltage (V-OC) in such wide-bandgap perovskite solar cells is crucial for a high overall power conversion efficiency (PCE). Here, we provide key insights into the factors affecting the V-OC in wide-bandgap perovskite solar cells. We show that the influence of the hole transport layer (HTL) on V-OC is not simply through its ionization potential but mainly through the quality of the perovskite-HTL interface. With effective interface passivation, we demonstrate perovskite solar cells with a bandgap of 1.72 eV that exhibit a V-OC of 1.22 V. Furthermore, by combining the high-V-OC perovskite solar cell with a c-Si solar cell, we demonstrate a perovskite-Si four-terminal tandem solar cell with a PCE of 27.1%, exceeding the record PCE of single-junction Si solar cells.

Country
Netherlands
Keywords

HALIDE-PEROVSKITE, Sustainability and the Environment, PHASE SEGREGATION, Energy Engineering and Power Technology, EFFICIENT, ENERGETICS, OPEN-CIRCUIT VOLTAGE, Fuel Technology, To be checked by Faculty, Chemistry (miscellaneous), Materials Chemistry, SDG 7 - Affordable and Clean Energy, Renewable Energy, SILICON, SDG 7 – Betaalbare en schone energie

  • BIP!
    Impact byBIP!
    citations
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    157
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 1%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 10%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 1%
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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
157
Top 1%
Top 10%
Top 1%
hybrid
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Related to Research communities
Energy Research