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Efficient “Light-soaking”-free Inverted Organic Solar Cells with Aqueous Solution Processed Low-Temperature ZnO Electron Extraction Layers

doi: 10.1021/am404291p
pmid: 24308270
Efficient “Light-soaking”-free Inverted Organic Solar Cells with Aqueous Solution Processed Low-Temperature ZnO Electron Extraction Layers
Low-temperature processes are unremittingly pursued in the fabrication of organic solar cells. The paper reports that the highly efficient and "light-soaking"-free inverted organic solar cell can be achieved by using ZnO thin films processed from the aqueous solution method at a low temperature. The inverted organic solar with an aqueous-processed ZnO thin film annealed at 150 °C shows an efficiency of 3.79%. Even when annealed at a temperature as low as 80 °C, the device still shows an efficiency of 3.71%. With the proper annealing temperature of 80 °C, the flexible device, which shows an efficiency of 3.56%, is fabricated on PET. This flexible device still keeps the efficiency above 3.40% after bent for 1000 times with a curvature radius of 50 mm. In contrast, a low annealing temperature leads to an inferior device performance when the ZnO thin film is processed from the widely used sol-gel method. The device with sol-gel processed ZnO annealed at 150 °C only shows a PCE of 1.3%. Furthermore, the device shows a strong "light-soaking" effect, which is not observed in the device containing an aqueous-processed ZnO thin film. Our results suggest that the adopted aqueous solution method is a more efficient low temperature technique, compared with the sol-gel method.
- Xidian University China (People's Republic of)
- National University of Singapore Singapore
- University of Electronic Science and Technology of China China (People's Republic of)
Inverted organic solar cell, Sol gel method, Aqueous solution method, Temperature, Water, Electrons, Thiophenes, 530, "Light-soaking" effect, Zinc oxide, Solar Energy, Polystyrenes, Zinc Oxide, Gels
Inverted organic solar cell, Sol gel method, Aqueous solution method, Temperature, Water, Electrons, Thiophenes, 530, "Light-soaking" effect, Zinc oxide, Solar Energy, Polystyrenes, Zinc Oxide, Gels
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