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Morphology of Methane Hydrate Formation in Porous Media

doi: 10.1021/ef4004818
Experiments at 8.0 MPa and 277.15 K were carried out in different porous media, such as silica sand and activated carbon, to observe the formation and dissociation of methane hydrate in a specially designed crystallizer for mophology observation. In silica sand bed, we observed a clear hydrate front moving across the bed in the crystallizer at the experimental conditions with 50 and 100% water saturation. The hydrate crystals were observed to form in the interstitial pore space available between the silica sand particles. Whereas in activated carbon bed experiments, hydrates were observed to nucleate on the surface of the activated carbon grain and then dissociate within the stable hydrate formation region. For the first time, we were able to observe this behavior of transient hydrate crystal formation/dissociation in the stable hydrate region in porous media. We postulated that the particle size, pore space, and water saturation level may play a role in the above phenomenon. A clear hydrate front movemen...
- National University of Singapore Singapore
- Singapore Institute of Technology Singapore
- Singapore Institute of Technology Singapore
- Imperial College London United Kingdom
- Chulalongkorn University Thailand
540, 620
540, 620
citations This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).149 popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.Top 1% influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).Top 10% impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.Top 1%
