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Work to Chemical Processes: The Relationship between Heat, Temperature, Pressure, and Process Complexity

doi: 10.1021/ie2004785
For a chemical process to be feasible, two levels of energy must be met: the heat and work requirements of the process. Whereas, for most processes, the heat requirement can easily be satisfied, supplying the amount of work needed is a major challenge and is usually the determinant of the process complexity. In some cases, heat, by virtue of its temperature, can satisfy the work requirement for a process; it is the simplest method for supplying work but could result in major irreversibility when applied inappropriately to a process. This article discusses different techniques that can be used to supply work to a process. A graphical approach, namely, the gh diagram, is used to analyze the heat and work requirements of chemical processes and to determine which method of supplying work is suitable for the process to be feasible and reversible. An ammonia process is analyzed as a case study, in which different methods of supplying work are compared and an attempt is made to elucidate the consequences of oper...
- University of the Witwatersrand South Africa
citations This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).13 popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.Top 10% influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).Top 10% impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.Average
