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Hydrogen Gas-Mediated Deoxydehydration/Hydrogenation of Sugar Acids: Catalytic Conversion of Glucarates to Adipates

descriptionPublicationkeyboard_double_arrow_right Article , Journal 03 Oct 2017 United States Publisher:American Chemical Society (ACS)Journal:Journal of the American Chemical Society, volume 139, pages 14,001-14,004 (issn: 0002-7863, eissn: 1520-5126,

Authors: Reed T. Larson; Andrew Samant; Jianbin Chen; Woojin Lee; Martin A. Bohn; Dominik M. Ohlmann; Stephan J. Zuend; +1 Authors

doi: 10.1021/jacs.7b07801

pmid: 28972364

Hydrogen Gas-Mediated Deoxydehydration/Hydrogenation of Sugar Acids: Catalytic Conversion of Glucarates to Adipates

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Abstract

The development of a system for the operationally simple, scalable conversion of polyhydroxylated biomass into industrially relevant feedstock chemicals is described. This system includes a bimetallic Pd/Re catalyst in combination with hydrogen gas as a terminal reductant and enables the high-yielding reduction of sugar acids. This procedure has been applied to the synthesis of adipate esters, precursors for the production of Nylon-6,6, in excellent yield from biomass-derived sources.

Country

United States

Related Organizations

Robert Bosch (Germany)
Germany
University of California System
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University of California, Berkeley
United States
BASF (United States)
United States
Robert Bosch (Germany)
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Keywords

Polymers, Adipates, Hydroxylation, Catalysis, Engineering, Affordable and Clean Energy, Caprolactam, Biomass, Esterification, Organic Chemistry, Sugar Acids, General Chemistry, 540, 620, Rhenium, Chemical sciences, Chemical Sciences, Hydrogenation, Oxidation-Reduction, Palladium, Hydrogen

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	influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).	Top 10%
	impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.	Top 1%