The effect of heat treatment of Ti and Ti–0.2 Pd alloys on their anodic oxidation was studied in deaerated 1% NaCl by means of anodic linear sweep voltammetry, SEM, TEM, EDS, optical microscopy and microhardness measurements. The specimens, as fabricated, consisted of α-phase only. The β-phase, intergranular or with a Widmansttaten type growth, was produced by heat treatment of the Ti–0.2 Pd alloys at the temperature range from 750 to 850 ∘C. The β-phase was transformed into the α′-phase during quenching. The current density against voltage curves for pure Ti and Ti–0.2 Pd, as fabricated or heat-treated, presented an initial plateau at about 1.5 V vs Ag/AgCl/KCl (3 M), an anodic peak at about 4.5 V and a current increase due to the pitting attack at about 10 V. The anodic peak was related to an oxide growth together with a solution electrolysis. Current spikes appeared at random from potentials about 8.3 V, which were related to film breakdown and repair events. The passive films of the alloys oxidized up to about 10 V presented oxidation bands parallel to the surface, with different oxygen content and microhardness, together with a structural transformation of the α′-phase under the titanium oxide layer. The similar behaviour of pure Ti and Ti–0.2 Pd alloys in front of pitting corrosion in chloride was due to such a structural transformation.