AbstractAdsorption cooling and desalination (ACD) system powered by renewable energy has been considered as a promising solution to solve interconnected global problems such as freshwater scarcity, high-cost air conditioning, CO2 emission, and global warming. In this work, a new nanoporous silica was synthesized through a self-assembly process using a combination of ionic and non-ionic surfactants. The silica has shown unique pore structures, including high surface area and large pore volume, as well as ideal pore size distribution. The new silica was deposited (coated) over the ligaments of aluminum foam for use as a sorption bed. An uncoated aluminum foam packed with conventional silica RD (regular density) particles serves as a baseline sorption bed. The freshwater production rate and cooling power produced using the two sorbents were compared. Silica RD outperforms the new silica for cooling while the new silica is far better for desalination application. Insights for such results are provided.