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Nature Energy
Article . 2019 . Peer-reviewed
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Design of low bandgap tin–lead halide perovskite solar cells to achieve thermal, atmospheric and operational stability

Authors: Jérémie Werner; Jérémie Werner; Camila de Paula; James A. Raiford; Stacey F. Bent; Maikel F.A.M. van Hest; Michael D. McGehee; +16 Authors

Design of low bandgap tin–lead halide perovskite solar cells to achieve thermal, atmospheric and operational stability

Abstract

Low bandgap tin–lead iodide perovskites are key components of all-perovskite tandem solar cells, but can be unstable because tin is prone to oxidation. Here, to avoid a reaction with the most popular hole contact, we eliminated polyethylenedioxythiophene:polystyrenesulfonate as a hole transport layer and instead used an upward band offset at an indium tin oxide–perovskite heterojunction to extract holes. To suppress oxidative degradation, we improved the morphology to create a compact and large-grained film. The tin content was kept at or below 50% and the device capped with a sputtered indium zinc oxide electrode. These advances resulted in a substantially improved thermal and environmental stability in a low bandgap perovskite solar cell without compromising the efficiency. The solar cells retained 95% of their initial efficiency after 1,000 h at 85 °C in air in the dark with no encapsulation and in a damp heat test (85 °C with 85% relative humidity) with encapsulation. The full initial efficiency was maintained under operation near the maximum power point and near 1 sun illumination for over 1,000 h. Low bandgap tin–lead perovskites are crucial to making efficient all-perovskite tandem solar cells but have so far shown poor stability. By removing the hole transport layer and improving film morphology, Prasanna et al. demonstrate a low-gap perovskite solar cell that is stable for 1,000 h under heat, light and atmospheric conditions.

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    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    251
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 0.1%
    influence
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    Top 10%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 0.1%
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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
251
Top 0.1%
Top 10%
Top 0.1%
bronze