The practical effects of incorporating artificial intelligence (AI) into Industry 5.0 smart city services are made evident by this empirical research. The use of AI-powered smart traffic management yields a noteworthy 32.94% rise in traffic volume, signifying a noteworthy progression towards improved urban mobility. AI waste management optimization results in a 5.71% increase in collection efficiency, highlighting the importance of operational effectiveness and resource conservation. The control of energy use shows an 8.57% decrease, confirming AI's importance in sustainable energy practices. AI-enhanced public safety offers dependable event prediction, indicating safer cityscapes. These results highlight AI's revolutionary potential and establish smart cities as safe, secure, and sustainable urban environments.