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EPJ Photovoltaics
Article . 2011 . Peer-reviewed
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EPJ Photovoltaics
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Article . 2011
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Novel texturing method for sputtered zinc oxide films prepared at high deposition rate from ceramic tube targets

Authors: Bunte, E.; Zhu, H.; Hüpkes, J.; Owen, J.;

Novel texturing method for sputtered zinc oxide films prepared at high deposition rate from ceramic tube targets

Abstract

Sputtered and wet-chemically texture etched zinc oxide (ZnO) films on glass substrates are regularly applied as transparent front contact in silicon based thin film solar cells. In this study, chemical wet etching in diluted hydrofluoric acid (HF) and subsequently in diluted hydrochloric acid (HCl) on aluminum doped zinc oxide (ZnO:Al) films deposited by magnetron sputtering from ceramic tube targets at high discharge power (~10 kW/m target length) is investigated. Films with thickness of around 800 nm were etched in diluted HCl acid and HF acid to achieve rough surface textures. It is found that the etching of the films in both etchants leads to different surface textures. A two steps etching process, which is especially favorable for films prepared at high deposition rate, was systematically studied. By etching first in diluted hydrofluoric acid (HF) and subsequently in diluted hydrochloric acid (HCl) these films are furnished with a surface texture which is characterized by craters with typical diameter of around 500 − 1000 nm. The resulting surface structure is comparable to etched films sputtered at low deposition rate, which had been demonstrated to be able to achieve high efficiencies in silicon thin film solar cells.

Country
Germany
Keywords

info:eu-repo/classification/ddc/600, TJ807-830, Renewable energy sources

  • BIP!
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    citations
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    15
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Average
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 10%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 10%
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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
15
Average
Top 10%
Top 10%
Green
gold
Related to Research communities
Energy Research