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Concentration fluctuations in fluid mixtures. II.

The method developed in a previous paper [R. Mazo, J. Chem. Phys. 129, 154101 (2008)] for extracting information on the size of relative fluctuations in multicomponent systems is tested on ten binary systems and one ternary system. For the binary systems, it is found that the approximation works well for mole fractions in the range of 0.15–0.85 in most cases. For the ternary case, the method inherently yields less information and is valid only over a more restricted range for the case studied (chloroform-methanol-acetone). It is found that the predicted ratio of number fluctuations is approximately equal to the ratio of molar volumes of the components.
- National Research Council Italy
- University of Oregon United States
- Institute for Chemical and Physical Processes Italy
- Kansas State University United States
- Kansas State University United States
Acetonitriles, Ethanol, Butanols, Methanol, Water, 1-Propanol, Octanes, Acetone, Alkanes, Thermodynamics, Chloroform, Carbon Tetrachloride
Acetonitriles, Ethanol, Butanols, Methanol, Water, 1-Propanol, Octanes, Acetone, Alkanes, Thermodynamics, Chloroform, Carbon Tetrachloride
citations This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).3 popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.Average influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).Average impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.Average
