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Article . 2015
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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
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Article . 2015
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Journal of Renewable and Sustainable Energy
Article . 2015 . Peer-reviewed
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Joule heating-assisted growth of Cu(In,Ga)Se2 solar cells

Authors: S Rampino; F Annoni; M Bronzoni; M Calicchio; E Gombia; M Mazzer; F Pattini; +1 Authors

Joule heating-assisted growth of Cu(In,Ga)Se2 solar cells

Abstract

We report on the development of an unconventional method for heating a Mo-coated substrate during the deposition of a Cu(In,Ga)Se2 (CIGS) layer by the pulsed electron deposition technique, to be used as absorber in thin film solar cells. This method is based on the application of a DC electrical power directly through the Mo back contact of the cell, converting electrical energy into heat by Joule effect. Since the current flows only on the superficial metal-coated region of the substrate, a localized heating of the surface can be achieved, thus limiting the heat losses. Due to the very efficient heat transfer to the thin Mo layer, a very little electrical power density (few W/cm2) is enough to achieve the required deposition temperature on the Mo surface, much lower compared to the traditional resistor- or lamp-based external heaters. The morphological and electrical properties of Joule-heated samples have been compared to those of CIGS films heated by a conventional external heater. As far as the structure concerns, a remarkable difference is revealed by Scanning Electron Microscopy analysis, indicating a significant enlargement of the CIGS grains size on Joule-heated samples. On the contrary, Capacitance-Voltage and Current-Voltage measurements evidence similar electrical features: both types of heated samples have a net free carrier concentration ≈5 × 1015 cm−3, resulting in a similar photovoltaic conversion efficiency (≈15%). The main recombination path, deduced from the dependence of VOC on the temperature, results to be the Shockley-Read-Hall mechanism in both types of the absorber layer. These results indicate that the Joule effect could be adopted as a feasible, low cost alternative heating method for growing high quality CIGS layers.

Country
Italy
Keywords

Molybdenum, Solar cells, Pulsed Electron Deposition, Thin film growth, Sputter deposition

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
5
Average
Average
Average
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