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Characterization of Recombination Properties and Contact Resistivity of Laser-Processed Localized Contacts From Doped Silicon Nanoparticle Ink and Spin-On Dopants

handle: 1885/233436
An increase in market share of very high-efficiency solar cell concepts, such as interdigitated back contact (IBC) solar cells, is typically limited by their high cost due to complex and expensive processing sequences. Implementation of localized laser-doped contacts is a promising route to reduce fabrication costs while maintaining the high-efficiency potential of such solar cell concepts, also offering the potential to use cheaper, upgraded metallurgical silicon which may otherwise be vulnerable to degradation when exposed to traditional high-temperature processing. In this work, we introduce novel test structures and perform numerical simulations to accurately determine the contact properties, namely, the recombination parameter J 0, c down to values of 300 fA cm–2 and contact resistivity ρc down to values of 1 × 10–4 Ω cm2. We analyze the performance of 30 μ m × 30 μ m-sized laser-doped localized contacts prepared using boron and phosphorus spin-on dopants and phosphorus-doped silicon nanoparticle ink. The laser-doped contacts characterized in this work allow for 23.7% efficient IBC solar cells as we demonstrate by numerical.
- Australian National University Australia
621
621
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