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Silicon Tunnel Junctions Produced by Ion Implantation and Diffusion Processes for Tandem Solar Cells

Authors: Bellanger, Pierre; Minj, Albert; Fave, Alain; Djebbour, Zakaria; Roques, Stephane; Slaoui, Abdelilah;

Silicon Tunnel Junctions Produced by Ion Implantation and Diffusion Processes for Tandem Solar Cells

Abstract

This work reports on the fabrication of silicon tunnel junctions that can be used in silicon-based bottom cells for tandem solar cells. The tunnel junction was formed on n-type monocrystalline silicon wafers using the following two different processes: 1) a thermal diffusion of boron followed by an arsenic ion implantation; and 2) successive implantation steps of boron and arsenic ions. For both the processes, a rapid thermal annealing step was used to activate the dopants and cure the defects generated by the ion implantation. The activated dopant distribution across the tunnel junction was determined by electrochemical capacitancevoltage (ECV) measurements. The quality of the device was assessed from the peak-to-valley ratio and peak current density of its currentvoltage characteristics, as well as the resistivity. As a significant result, a peak current density value and a peak-to-valley ratio of approximately 50 A/cm2 and 1.7, respectively, were obtained for two consecutive implantations of boron and arsenic, followed by thermal annealing at 925C for 30 min. A very narrow depletion zone of 3.9nm was calculated from the ECV dopant concentrations measurements under full depletion approximation. Finally, solar cells fabricated using this optimized process resulted in a conversion efficiency of 10.1 against 12 obtained from the reference monocrystalline solar cell.

Country
France
Keywords

Silicon, Tunnel junction, [SPI.NRJ]Engineering Sciences [physics]/Electric power, Tandem solar cells, 530, [SPI.MAT]Engineering Sciences [physics]/Materials, Ion implantation, [SPI.GPROC]Engineering Sciences [physics]/Chemical and Process Engineering, Thermal diffusion, [SPI.NRJ] Engineering Sciences [physics]/Electric power

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    5
    popularity
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    Top 10%
    influence
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    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
5
Top 10%
Average
Average
Related to Research communities
Energy Research