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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao IEEE Journal of Phot...arrow_drop_down
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IEEE Journal of Photovoltaics
Article . 2020 . Peer-reviewed
License: IEEE Copyright
Data sources: Crossref
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Long Carrier Diffusion Length and Slow Hot Carrier Cooling in Thin Film Mixed Halide Perovskite

Authors: Kamlesh Kumar Chauhan; Sayan Prodhan; Dibyendu Ghosh; Pradney Waghale; Sayan Bhattacharyya; Pranab Kumar Dutta; Prasanta Kumar Datta;

Long Carrier Diffusion Length and Slow Hot Carrier Cooling in Thin Film Mixed Halide Perovskite

Abstract

The long diffusion length is the key to achieve remarkable power conversion efficiency and delayed hot carriers (HCs) relaxation helps to overcome the theoretical Shockley–Queisser limit in perovskite photovoltaic. Here, we investigate the incident photon density dependent bandedge bleaching and HCs dynamics in thin film methyl-ammonium lead iodide-chloride (mixed halide) perovskite using transient absorption spectroscopy. The bandedge bleaching dynamics shows the radiative recombination rate constant of the order of ∼10−11 cm−3 s−1 results in the maximum carrier diffusion length of the order of ∼10 μm. The HCs dynamics indicates cooling occurs by longitudinal-optical (LO) phonon emission in early ∼800 fs via Frohlich electron–phonon interaction at low-carrier concentration (∼1.7 × 1018 cm−3) and an efficient phonon bottleneck due to the delayed LO-phonon decay by two order of magnitude about ∼11 ± 1.3 ps at high carrier density (∼1019 cm−3). Our finding shows the potential of thin film mixed halide perovskite in HCs photovoltaic and light emission application.

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
14
Top 10%
Average
Top 10%
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