This work reports on the significant enhancement of the thermal properties of the FR3 natural ester dielectric oil after the addition of pentyl-graphene nanosheets, as confirmed by thermal diffusivity and specific heat studies at different concentrations and temperatures (30 degrees C-90 degrees C). Experimental results of the dielectric constant demonstrated a constant value in the kHz region while increased in the low-frequency region, decreased with increased temperature, and saturated at 0.008% w/w concentration. In addition, light absorption is used for a better understanding of the properties variation upon changing graphene's concentration as a method to estimate the agglomeration level. The optimum concentration for its best performance in terms of thermal and dielectric properties is 0.008% w/w, whereby the thermal diffusivity and the dielectric constant increased by 43.04% and 6.18%, respectively. Web of Science 29 2 518 510