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Intermediate-Temperature NOx Sensor Based on an In[sup 3+]-Doped SnP[sub 2]O[sub 7] Proton Conductor

doi: 10.1149/1.2193073
A potentiometric NOx sensor using a proton-conducting Sn 0.9 In 0.1 P 2 O 7 electrolyte with a PtRh/C working electrode was fabricated to study sensing properties for NO and NO 2 at intermediate temperatures. The sensor showed electromotive force (emf) responses to changes in NO and NO 2 concentrations. Interestingly, the emf values for both NO and NO; increased in the positive direction with increasing gas concentration. The sensing mechanism was shown to be based on a mixed potential at the working electrode through measurements of the polarization curves of NO or NO 2 and water vapor.
indium compounds, ionic conductivity, electrochemical sensors, tin compounds, electrolytes, nitrogen compounds, electrochemical electrodes
indium compounds, ionic conductivity, electrochemical sensors, tin compounds, electrolytes, nitrogen compounds, electrochemical electrodes
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