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Gas Concentration Impedance of Solid Oxide Fuel Cell Anodes

Authors: Wolfgang G. Bessler; Stefan Gewies;

Gas Concentration Impedance of Solid Oxide Fuel Cell Anodes

Abstract

This series of papers presents details of numerical studies of the nature of the impedance of solid oxide fuel cell (SOFC) anodes caused by gas-phase transport processes. The present part treats channel geometries where gases are transported parallel to the electrode surface. Two cases are investigated: (i) channel flow by forced convection, a typical situation in planar stack segments; and (ii) channel diffusion without convective flow, a typical situation in laboratory-scale single-chamber experiments using symmetrical cells. Current/voltage curves and electrochemical impedance spectra are simulated based on the Navier-Stokes transport equations and nonlinear electrochemistry models. Both channel flow and channel diffusion cause a capacitive behavior in the form of an resistance-capacitive (RC)-type semicircle in the Nyquist diagram. Its resistance and relaxation frequency strongly depend on operation parameters (gas concentration, flow rate, temperature, electrochemical polarization) and geometry (channel length and cross-sectional area). The model predictions are in good quantitative agreement with four different experimental studies published in the literature. The simulation approach thus allows a physically based assignment of observed gas concentration impedance processes.

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    97
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    influence
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Found an issue? Give us feedback
citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
97
Top 1%
Top 10%
Top 10%