This paper investigated the performance of a bioethanol-fed Solid Oxide Fuel Cell (SOFC) system integrated with a distillation column (SOFC-D). Excess heat from the SOFC system was directly utilized in the distillation column where bioethanol (5 mol%) was purified to a desired concentration before feeding to the SOFC system consisting of an air heater, an ethanol/water heater, a reformer, an SOFC preheater, an SOFC stack and an afterburner. The SOFC-D system was simulated using Aspen PlusTM for the distillation portion and MatlabTM for the SOFC portion. The effects of operating parameters; i.e., ethanol concentration, ethanol recovery, fuel utilization and operating voltage on the performance and energy involved in the SOFC-D system (e.g. distillation energy: QD and the net exothermic heat of the SOFC system: QSOFC,Net) were examined. In addition, the performance of the SOFC-D system at the energy sufficient point where QD = QSOFC,Net was considered. The integration of the distillation column with the SOFC system was found to offer superior SOFC performance. The ethanol recovery and fuel utilization significantly influenced the overall electrical efficiency and power density. Quite low performances are obtained when one operated the SOFC-D without an external heat source. The maximum overall efficiency and power density (~35% and 0.22 W cm-2) occured at an ethanol recovery of 80% and Uf of 90%.