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Research at ASB
Article . 2008
Data sources: Research at ASB
Journal of The Electrochemical Society
Article . 2008 . Peer-reviewed
Data sources: Crossref
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Solid Oxide Electrolysis Cells: Microstructure and Degradation of the Ni/Yttria-Stabilized Zirconia Electrode

Authors: Hauch, Anne; Ebbesen, Sune; Jensen, Søren Højgaard; Mogensen, Mogens Bjerg;

Solid Oxide Electrolysis Cells: Microstructure and Degradation of the Ni/Yttria-Stabilized Zirconia Electrode

Abstract

Solid oxide fuel cells produced at Riso DTU have been tested as solid oxide electrolysis cells for steam electrolysis by applying an external voltage. Varying the sealing on the hydrogen electrode side of the setup verifies that the previously reported passivation over the first few hundred hours of electrolysis testing was an effect of the applied glass sealing. Degradation of the cells during long-term galvanostatic electrolysis testing [850°C, -1/2 A/cm 2 , p(H 2 O)/p(H 2 ) = 0.5/0.5] was analyzed by impedance spectroscopy and the degradation was found mainly to be caused by increasing polarization resistance associated with the hydrogen electrode. A cell voltage degradation of 2%/1000 h was obtained. Postmortem analysis of cells tested at these conditions showed that the electrode microstructure could withstand at least 1300 h of electrolysis testing, however, impurities were found in the hydrogen electrode of tested solid oxide electrolysis cells. Electrolysis testing at high current density, high temperature, and a high partial pressure of steam [-2 A/cm 2 , 950°C, p(H 2 O) = 0.9 atm] was observed to lead to significant microstructural changes at the hydrogen electrode-electrolyte interface.

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    citations
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    285
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 1%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 1%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 1%
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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
285
Top 1%
Top 1%
Top 1%
Green
bronze