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Journal of The Electrochemical Society
Article . 2011 . Peer-reviewed
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Electrochemical Impedance Spectroscopy Study into the Effect of Titanium Dioxide Added to the Alkaline Manganese Dioxide Cathode

Authors: Bailey, Mark R.; Donne, Scott W.;

Electrochemical Impedance Spectroscopy Study into the Effect of Titanium Dioxide Added to the Alkaline Manganese Dioxide Cathode

Abstract

A combination of step potential electrochemical spectroscopy (SPECS) and electrochemical impedance spectroscopy (EIS) has been used to examine the effect of anatase titanium dioxide added to the alkaline manganese dioxide electrode. The inclusion of titanium dioxide was found to improve performance by lowering the resistance to charge transfer at the MnO 2 /electrolyte/graphite interface. Furthermore, a consideration of mass transport processes within the electrode indicates that titanium ions may become incorporated into the γ-MnO 2 lattice upon cycling, impacting H + /e − mass transport.

Country
Australia
Keywords

electrochemical impedance spectroscopy, electrolytes, charge exchange, electrochemical electrodes

  • BIP!
    Impact byBIP!
    citations
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    25
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 10%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 10%
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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
25
Top 10%
Top 10%
Top 10%
bronze