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The Influence of Electrode Constituents on Hydrogen Evolution Reaction on Phosphate W- and Mo-Bronze-Based Electrodes

descriptionPublicationkeyboard_double_arrow_right Article 01 Oct 2022 Serbia Publisher:The Electrochemical SocietyJournal:Journal of The Electrochemical Society, volume 169, page 106,508 (issn: 0013-4651, eissn: 1945-7111,

Authors: Maja Pagnacco; Smilja Marković; Jelena Potočnik; Vesna Krstić; Pavle Tančić; Miloš Mojović; Zorica Mojović;

doi: 10.1149/1945-7111/ac96ab

handle: 21.15107/rcub_dais_13493

The Influence of Electrode Constituents on Hydrogen Evolution Reaction on Phosphate W- and Mo-Bronze-Based Electrodes

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Abstract

Phosphate tungsten bronze (WPB) and phosphate molybdenum bronze (MoPB) were synthesized and modified with rhenium. The existing phases were established by X-ray powder diffraction (XRPD), electron paramagnetic spectroscopy (EPR) and Field emission scanning electron microscopy (FESEM). The electroactivity of bronze samples, with and without rhenium for hydrogen evolution reaction (HER) was tested. The influence of carbon black presence in the catalytic ink on the electrochemical activity was investigated. Collected results provide insight into the effects of the constituents of an electrode on its electrochemical activity.

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Serbia

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Keywords

electrochemical properties, tungsten bronzes, electrocatalysts, molybdenum, impedance spectra, acid, oxide, structural - characterization, proton

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CER - Central Repository of the Institute of Chemistry, Technology and Metallurgy, University of Belgrade 39 101
DAIS - Digitalni arhiv izdanja SANU 39 1
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