The credible sources of fossil energy efficiently are a vital cause of economic growth and considerable influence on adequate security. Whereas radiant energy positively enhances or ostensibly promotes socio-economic stability and the controlled environment. The fossil energy sources supply has become progressively stern in China and reconnoitering the beta decoupling relationships between CO2 emissions, GDP, energy consumption, electricity consumption, value-added industries, and population. The results will be favorable for illustrative the security of the valuable resources. This study adopts the extended stochastic model (STIRPAT) with Beta Decoupling Techniques (BDT). This modern technique merely employs the decoupling situation by the alpha and beta effects from 1989 to 2018 and calculates the % change in CO2 emissions by GDP growth and energy consumption. The estimated results represent negative and economic growth depends on coal and natural gas. First, CO2 emissions annually increasing cause of rapid growth, energy consumption, and electricity production, and the structural contradiction of energy remained static. Second, the Value-added industries estimated that CO2 emissions reduce by primary industries. Third, the decoupling states of CO2 emissions and population show an inverse relationship. This paper tentatively suggests China is sustainable, naturally strengthens energy output, transmutes the energy consumption structure, and advances development policies under environmental circumstances.