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Numerical Simulations of Heterogeneous Chemical Reactions Coupled to Fluid Flow in Varying Thermal Fields

Authors: Carnahan, C.L.;

Numerical Simulations of Heterogeneous Chemical Reactions Coupled to Fluid Flow in Varying Thermal Fields

Abstract

ABSTRACTA numerical simulator of reactive chemical transport with coupling from precipitation-dissolution reactions to fluid flow, via changes of porosity and permeability, is applied to precipitation-dissolution of quartz and calcite in spatially and temporally variable fields of temperature. Significant effects on fluid flow are found in the quartz-silicic acid system in the presence of a persistent, strong gradient of temperature. Transient heat flow in the quartz-silicic acid system and in a calcite-calcium ion-carbonato species system produces vanishingly small effects on fluid flow.

Country
United States
Keywords

Terrestrial-- Chemicals Monitoring & Transport-- (1990-), 58 Geosciences, Carbonate Minerals, Temperature Gradients, Precipitation, Permeability, Radioactive Materials, Temperature Effects, Hydraulic Conductivity, 37 Inorganic, Radioactive Waste Disposal, Waste Management, 052002 -- Nuclear Fuels-- Waste Disposal & Storage, Radioactive Waste Management, Radioactive Wastes, 12 Management Of Radioactive And Non-Radioactive Wastes From Nuclear Facilities, 54 Environmental Sciences, Materials, Fluid Flow, Computerized Simulation, Minerals, Numerical Analysis, Organic, 580000 -- Geosciences, Waste Disposal, Calcite, Chemical Reactions, Quartz, Heat Transfer, Management, Separation Processes, 540220 -- Environment, Energy Transfer, Wastes 400201* -- Chemical & Physicochemical Properties, Physical And Analytical Chemistry, Silicate Minerals, Oxide Minerals, Porosity, Simulation, Mathematics

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
4
Average
Average
Average
Green
bronze
Related to Research communities
Energy Research