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A Study of the Hydration and Dehydration Transitions of Srcl2 Hydrates for Use in Heat Storage

We have experimentally determined the main thermodynamic properties of SrCl2, a potentially promising salt for thermochemical heat storage. We found a high energy density of 2.4 ± 0.1 GJ/m3 and proved full cyclability for at least 10 cycles going from the anhydrate to the hexahydrate without chemical degradation. We have experimentally determined the thermodynamic equilibria for each individual transition and the corresponding metastable zones. We find that the metastable zone is widest for the anhydrate to monohydrate transition and decreases with each subsequent hydration step. We have also established that the observed nucleation kinetics are highly dependent on the preparation of the sample. Depending on the preparation conditions, some seeds of the precursor phase can remain in the sample thereby influencing the induction times for the transition. In heat storage applications we recommend selecting conditions well away from the phase transition lines (at least outside the metastable zone) and to leave some seeds of the phase to be transferred in order to increase the transition speed.
- Delft University of Technology Netherlands
- Technical University Eindhoven Netherlands
- Radboud University Nijmegen Netherlands
- Technical University Eindhoven Netherlands
- Technical University Eindhoven TU Eindhoven Research Portal Netherlands
Thermochemical analysis, SrCl, Solid State Chemistry, SrCl2, Thermochemical heat storage, SDG 7 - Affordable and Clean Energy, SDG 7 – Betaalbare en schone energie, Hydration/dehydration cycling
Thermochemical analysis, SrCl, Solid State Chemistry, SrCl2, Thermochemical heat storage, SDG 7 - Affordable and Clean Energy, SDG 7 – Betaalbare en schone energie, Hydration/dehydration cycling
citations This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).23 popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.Top 10% influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).Average impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.Top 10%
