In this research, the performance of vanadium redox flow batteries (VRFBs) in grid-connected energy storage systems centering on frequency and power sharing using voltage source inverters was evaluated. VRFBs are increasingly promising due to their scalability and long lifespan. We explore the impact of voltage source inverters on the frequency of the power supply when there is a change in load and power sharing between the grid and VRFB through MATLAB simulations. The test system demonstrates a storage system at an 11-kV substation and considers a load profile commencing from residential and commercial consumers. The outcome of this study reveals that VRFBs provide the required power to maintain load demand. Due to fast response time, VRFBs also regulate the frequency efficiently during the change in load demand and maintaining current total harmonic distortions (THDs). This research confirms the design and operation of VRFB-based energy storage systems, contributing to resilient grid infrastructure and reliable power distribution systems.