The development of energy-efficient technologies at all stages of a building’s life cycle is essential to achieving sustainable development goals. The object of the study is climate-adaptive façade structures with air gaps in the form of a Trombe wall and a double-skin façade. Cases using phase-change materials (PCM) and photovoltaic modules (PV) in climate-adaptive structures are analyzed separately. The research method is aimed to review and analyze the energy-saving potential from integrating the Trombe wall or double-skin façade in buildings. The work systematizes full-scale, physical, and mathematical experiments. Articles from Scopus and Web of Science systems from 2001 to 2022 inclusive were subject to consideration. The article presents a statistical analysis given by the scientific community on the current topic’s dynamics. The study’s significance is characterized by a lack of knowledge on the behavior of the mentioned façade systems in various climate zones and for different buildings types. The results have shown that comprehensive studies on the investigated systems are significant and can serve for further designs and energy efficiency improvements. For the first time, a scientometric analysis of articles on the topic “Climate-adaptive façades” was compiled.