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Complex Metal Hydrides for Hydrogen, Thermal and Electrochemical Energy Storage

Authors: Craig E. Buckley; Torben R. Jensen; Kasper T. Møller; Dorthe Bomholdt Ravnsbæk; Drew A. Sheppard; Drew A. Sheppard; Hai Wen Li; +1 Authors

Complex Metal Hydrides for Hydrogen, Thermal and Electrochemical Energy Storage

Abstract

Hydrogen has a very diverse chemistry and reacts with most other elements to form compounds, which have fascinating structures, compositions and properties. Complex metal hydrides are a rapidly expanding class of materials, approaching multi-functionality, in particular within the energy storage field. This review illustrates that complex metal hydrides may store hydrogen in the solid state, act as novel battery materials, both as electrolytes and electrode materials, or store solar heat in a more efficient manner as compared to traditional heat storage materials. Furthermore, it is highlighted how complex metal hydrides may act in an integrated setup with a fuel cell. This review focuses on the unique properties of light element complex metal hydrides mainly based on boron, nitrogen and aluminum, e.g., metal borohydrides and metal alanates. Our hope is that this review can provide new inspiration to solve the great challenge of our time: efficient conversion and large-scale storage of renewable energy.

Countries
Denmark, Australia
Keywords

N-H SYSTEM, Technology, 670, PEROVSKITE-TYPE HYDRIDE, solid-state electrolytes, Complexmetal hydrides, Thermal energy storage, hydrogen storage, fuel cell, X-RAY-DIFFRACTION, CRYSTAL-STRUCTURE, MAGNESIUM HYDRIDE, Electrodes, LITHIUM-ION BATTERIES, HIGH-TEMPERATURE HEAT, SODIUM SUPERIONIC CONDUCTION, T, Fuel cell, thermal energy storage, Hydrogen storage, 540, 620, electrodes, Solid-state electrolytes, complex metal hydrides, 2 SOLVENT ADDUCTS, ALUMINUM-HYDRIDE

  • BIP!
    Impact byBIP!
    citations
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    182
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 1%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 10%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 1%
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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
182
Top 1%
Top 10%
Top 1%
Green
gold