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Sub- and Supercritical Water Liquefaction of Kraft Lignin and Black Liquor Derived Lignin

Authors: Lappalainen, Jukka; Baudouin, David; Hornung, Ursel; Schuler, Julia; Melin, Kristian; Bjelić, Saša; Vogel, Frédéric; +3 Authors

Sub- and Supercritical Water Liquefaction of Kraft Lignin and Black Liquor Derived Lignin

Abstract

To mitigate global warming, humankind has been forced to develop new efficient energy solutions based on renewable energy sources. Hydrothermal liquefaction (HTL) is a promising technology that can efficiently produce bio-oil from several biomass sources. The HTL process uses sub- or supercritical water for producing bio-oil, water-soluble organics, gaseous products and char. Black liquor mainly contains cooking chemicals (mainly alkali salts) lignin and the hemicellulose parts of the wood chips used for cellulose digestion. This review explores the effects of different process parameters, solvents and catalysts for the HTL of black liquor or black liquor-derived lignin. Using short residence times under near- or supercritical water conditions may improve both the quality and the quantity of the bio-oil yield. The quality and yield of bio-oil can be further improved by using solvents (e.g., phenol) and catalysts (e.g., alkali salts, zirconia). However, the solubility of alkali salts present in black liquor can lead to clogging problem in the HTL reactor and process tubes when approaching supercritical water conditions.

Countries
Germany, Finland
Keywords

Technology, ddc:600, lignin from black liquor, ta1171, black liquor, SDG 7 - Affordable and Clean Energy, ta218, 219 Environmental biotechnology, ta113, ta212, ta214, 660, T, hydrothermal liquefaction, 600, Lignin from black liquor, info:eu-repo/classification/ddc/600, Black liquor, Hydrothermal liquefaction

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    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 1%
    influence
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    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 1%
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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
61
Top 1%
Top 10%
Top 1%