The impact of the use of cargo bicycles for delivery processes on the environment is undeniably positive: it leads to the reduction of pollutants, noise, and vibrations caused by traditional vehicles; decreases traffic jams; causes more effective use of public space; and others. But how should such an effect be measured? What tools should be used to justify the necessity for change to more sustainable means of transport? How can we improve the state of the environment considering the interests of logistics service providers? There is a large amount of scientific literature dedicated to this problem: by using different modeling approaches, authors attempt to address the issue of sustainable transport. This paper conducts a literature review in the field of green cargo deliveries, investigates the benefits and drawbacks of integrating cargo bikes in urban logistics schemes, and examines methodologies and techniques for evaluating the impact of using cargo bicycles on the environment. By providing an opportunity to get acquainted with the situation in the sphere of green deliveries, the authors aim to encourage a breakthrough in the field of sustainable transport that may be achieved by using cargo bikes in modern cities. We review the existing approaches and tools for modeling transport emissions and state the significant positive environmental consequences.