The determination of methane content of coal seams is conducted in hard coal mines in order to assess the state of methane hazard but also to evaluate gas resources in the deposit. In the world’s mining industry, natural gas content in coal determination is usually based on direct methods. It remains the basic method in Poland as well. An important element in the determination procedure is the gas loss that occurs while collecting a sample for testing in underground conditions. In the method developed by the authors, which is a Polish standard, based on taking a sample in the form of drill cuttings, this loss was established at a level of 12%. Among researchers dealing with the methane content of coal, there are doubts related to the procedures adopted for coal sampling and the time which passes from taking a sample to enclosing it in a sealed container. Therefore, the studies were designed to evaluate the degree of degassing of the sample taken in the form of drill cuttings according to the standard procedure and in the form of the drill core from a coal mine roadway. The results show that the determinations made for the core coincide with the determinations made for the drill cutting samples, with the loss of gas taken into account.