This article deals with the influence of temperature on the lightning impulse breakdown voltage (LI BDV) of mineral oil in a non-uniform electric field. The experiments were performed in point–plane electrode arrangements under a standard lightning impulse voltage of negative polarity. The LI BDV for the temperatures of 20, 40, 60, 80, 100 and 110 °C was measured using a step method with registration of the light signals emitted during pre-breakdown and breakdown phases. The average propagation velocity was also determined. The results confirm that the mineral oil tested under LI voltage behaves similarly to AC voltage-based stress. The LI BDV increases with temperature up to 100 °C and then tends to decrease. The results demonstrated that viscosity dependent processes are responsible for increasing the LI BDV with temperature up to the 100 °C; and liquid vapor formation processes are responsible for decreasing the LI BDV at temperatures equal to and higher than 100 °C.