The power sector plays a significant role in carbon neutrality strategies, and the grid system is a crucial part of the power sector. In particular, with less mitigation potential from technology efficiency, the credit from whole life cycles is critical. This paper describes the investigation of the environmental impacts of various scenarios from the perspective of life cycles. By using the life cycle assessment (LCA) method, various grid systems are examined as a case study, including a traditional, renewable energy, and power storage grid system, as well as a microgrid, in Guangdong. The results highlight the fact that with the systematic improvement of a grid, significant environmental benefits can be achieved. For a grid system, optimization through technology has significant carbon reduction effects even if the power grid structure is not changed. Using renewable energy instead of traditional fuel can reduce the emission of 0.05 kg of CO2-equivalent greenhouse gas per 1 kWh of electricity produced, which is 7.9% of the baseline, and microgrid technology leads to a much greater carbon reduction potential of 23.8% of the baseline. The role of energy storage is undervalued due to the limitations of the data.