The dependence of road transport on fossil fuels and its contribution to greenhouse gas (GHG) and pollutant emissions are main concerns leading to the need for shifting toward alternative energy sources and, namely, electromobility. The current paper aims to identify the key determinants affecting the consumer adoption of electric vehicles (EVs), focusing on private passenger cars. Toward this purpose, a systematic review of recent international literature is conducted in order to identify motivators and barriers, which are then categorized following the PESTLE (Political–Economic–Social–Technological–Legal–Environmental) approach. Based on the review results, main policy implications and recommendations are discussed. A main conclusion is that the recent literature highlights a wide array of determinants, without converging as to which ones are the most influential regarding EV adoption by consumers. Another conclusion is that the environmental aspects are less important for consumers than anticipated, despite the concerns about climate change and renewable energy transition.