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Energies
Article . 2022 . Peer-reviewed
License: CC BY
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Energies
Article . 2022
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Transient Multi-Physics Modeling and Performance Degradation Evaluation of Direct Internal Reforming Solid Oxide Fuel Cell Focusing on Carbon Deposition Effect

Authors: Zheng Li; Guogang Yang; Qiuwan Shen; Shian Li; Hao Wang; Jiadong Liao; Ziheng Jiang; +1 Authors

Transient Multi-Physics Modeling and Performance Degradation Evaluation of Direct Internal Reforming Solid Oxide Fuel Cell Focusing on Carbon Deposition Effect

Abstract

The performance degradation issue caused by carbon deposition has limited the commercial application of natural-gas-fueled solid oxide fuel cells. Most previous corresponding studies are based on thermodynamic equilibrium analyses, while long-term transient evaluation work is lacking. Therefore, a transient multi-physics numerical model is developed in present work. The corresponding long-term performance degradation evaluation is then conducted. The results show that, for a direct internal reforming solid oxide fuel cell, the increase in carbon deposition and deterioration of performance degradation were concentrated in the first 180 days of steady−state operation and slowed down at the later stage. The electrode inlet rapidly developed a high concentration of carbon deposition after 180 days of steady−state operation. The deposited carbon deteriorated the gas transport and decayed reaction activity within the porous electrode, eventually inducing a deactivation zone with 0 current density at the inlet. Key measures to inhibit carbon deposition should be implemented within the first 180 days of operation, and the pre-reformed operation of natural gas is encouraged for natural-gas-fueled solid oxide fuel cells.

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Keywords

Technology, T, transient multi-physics modeling, long-term performance evaluation, solid oxide fuel cell, solid oxide fuel cell; carbon deposition effect; transient multi-physics modeling; long-term performance evaluation, carbon deposition effect

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
1
Average
Average
Average
gold