It is critical and challenging to develop high performance transition metal phosphides (TMPs) electrocatalysts for oxygen evolution reaction (OER) to address fossil energy shortages. Herein, we report the synthesis of Co2P embedded in N-doped porous carbon (Co2P@N-C) via a facile one-step strategy. The obtained catalyst exhibits a lower overpotential of 352 mV for OER at a current density of 10 mA cm−2 and a small Tafel slope of 84.6 mV dec−1, with long-time reliable stability. The excellent electrocatalytic performance of Co2P@N-C can be mainly owed to the synergistic effect between the Co2P and highly conductive N-C substrate, which not only affords rich exposed active sites but also promotes faster charge transfer, thus significantly promoting OER process. This work presents a promising and industrially applicable synthetic strategy for the rational design of high performance nonnoble metal electrocatalysts with enhanced OER performance.