Previous studies have shown that shale oil mobility depends on the relative content of free oil and adsorbed oil. However, the research on how to establish a shale oil mobility evaluation is relatively insufficient. This study aims to use pyrolysis data before and after extraction to accurately identify the content of free oil and adsorbed oil, analyze the influencing factors of shale oil mobility, characterize the hydrocarbon generation and expulsion process, and evaluate shale oil mobility. We utilized an integrated mineralogical and geochemical dataset from the PS18-1 well in the Liutun Sag, Dongpu Depression, Bohai Bay Basin. The results show that the adsorption capacity of type I organic matter (OM) on shale oil is greater than that of type II OM, the OM abundance is of great significance to shale oil mobility, and that quartz and feldspar can promote shale oil mobility. The Tmax corresponding to the threshold of hydrocarbon expulsion is 438~440 °C, and the oil saturation index (OSI) is about 158 mg/g TOC. There are four small intervals: a (3257 m~3260 m), b (3262 m~3267 m), c (3273 m~3278 m), and d (3281 m~3282 m) meeting the conditions of hydrocarbon expulsion. Large-scale hydrocarbon expulsion occurred in interval a, a small amount of hydrocarbon expulsion in interval b, a large amount of hydrocarbon expulsion in interval c, and almost no hydrocarbon expulsion in interval d. Based on the crossplot of S1 and TOC, combined with other parameters such as OSI, hydrocarbon generation potential (HGP), and free and adsorbed oil, we established an evaluation chart of shale oil mobility and divided it into five categories: A, B, C, D, and E. While categories A and C have good mobility and great resource potential, categories B and D have relatively poor mobility and medium resource potential, and category E has little mobility and is an invalid resource.