The roads we travel daily are exposed to several energy sources (mechanical load, solar radiation, heat, air movement, etc.), which can be exploited to make common systems and apparatus for roadways (i.e., lighting, video surveillance, and traffic monitoring systems) energetically autonomous. For decades, research groups have developed many technologies able to scavenge energy from the said sources related to roadways: electromagnetism, piezoelectric and triboelectric harvesters for the cars’ stress and vibrations, photovoltaic modules for sunlight, thermoelectric solutions and pyroelectric materials for heat and wind turbines optimized for low-speed winds, such as the ones produced by moving vehicles. Thus, this paper explores the existing technologies for scavenging energy from sources available on roadways, both natural and related to vehicular transit. At first, to contextualize them within the application scenario, the available energy sources and transduction mechanisms were identified and described, arguing the main requirements that must be considered for developing harvesters applicable on roadways. Afterward, an overview of energy harvesting solutions presented in the scientific literature to recover energy from roadways is introduced, classifying them according to the transduction method (i.e., piezoelectric, triboelectric, electromagnetic, photovoltaic, etc.) and proposed system architecture. Later, a survey of commercial systems available on the market for scavenging energy from roadways is introduced, focusing on their architecture, performance, and installation methods. Lastly, comparative analyses are offered for each device category (i.e., scientific works and commercial products), providing insights to identify the most promising solutions and technologies for developing future self-sustainable smart roads.