Recently, many activities have been undertaken to reduce the negative impact of transport on the environment, e.g., using propulsion sources and consumed energy. Electric and hybrid vehicles are becoming more and more popular. Methods of measuring the emissivity of the means of transport as well as devices for determining measurements are being developed. This work presents an indicator method (IM) for determining the emissivity of road transport, while omitting the use of quite complicated and expensive research equipment. For typical road vehicles, it is possible to determine the emissivity means of transport, taking into account statistical data. The values of the indicators selected, based on statistical data analysis, were verified by comparing their values with the results of the actual emissivity of air pollutants. As part of the research work, the emissivity values of selected means of transport in a distribution company were determined using the IM method. The results were compared with the actual emissivity measurements. The method of indicative determination of emissivity makes it possible to estimate the initial emissivity level, knowing the type of vehicle and the distance performed as part of the transport work. Thanks to a simple and uncomplicated method, delivery planning can become more sustainable, and the selection of less emissive means of transport can contribute to reducing the negative impact of transportation on the environment.