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Energies
Article . 2023 . Peer-reviewed
License: CC BY
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Energies
Article . 2023
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Numerical Simulation of Processes in an Electrochemical Cell Using COMSOL Multiphysics

Authors: Iliya K. Iliev; Azamat R. Gizzatullin; Antonina A. Filimonova; Natalia D. Chichirova; Ivan H. Beloev;

Numerical Simulation of Processes in an Electrochemical Cell Using COMSOL Multiphysics

Abstract

Fuel cells are a promising source of clean energy. To find optimal parameters for their operation, modeling is necessary, which is quite difficult to implement taking into account all the significant effects occurring in them. We aim to develop a previously unrealized model in COMSOL Multiphysics that, on one hand, will consider the influence of electrochemical heating and non-isothermal fluid flow on the temperature field and reaction rates, and on the other hand, will demonstrate the operating mode of the Solid Oxide Fuel Cell (SOFC) on carbonaceous fuel. This model incorporates a range of physical phenomena, including electron and ion transport, gas species diffusion, electrochemical reactions, and heat transfer, to simulate the performance of the SOFC. The findings provide a detailed view of reactant concentration, temperature, and current distribution, enabling the calculation of power output. The developed model was compared with a 1-kW industrial prototype operating on hydrogen and showed good agreement in the volt-ampere characteristic with a deviation not exceeding 5% for the majority of the operating range. The fuel cell exhibits enhanced performance on hydrogen, generating 1340 W/m2 with a current density of 0.25 A/cm2. When fueled by methane, it produces 1200 W/m2 at the same current density. Using synthesis gas, it reaches its peak power of 1340 W/m2 at a current density of 0.3 A/cm2.

Keywords

Technology, reactants concentration, T, power output calculation, electrochemical reactions, fuel cell modelling, SOFC (solid oxide fuel cell), COMSOL Multiphysics

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
10
Average
Average
Top 10%
gold
Related to Research communities
Energy Research