As the presence of renewable energy production grows, so does the need to find alternative solutions for long–term energy storage. One solution may be hydrogen, and more generally, power-to-gas systems, which could allow energy storage for longer periods than batteries. However, the problem of hydrogen storage remains a limitation to the deployment of this technology. A possible solution for the hydrogen storage could be metal hydrides. In this work, a power-to-gas system based on a 2.5kW commercial electrolyzer coupled to a pair of AB2-type metal hydride cylinders with a total volume of 4L is studied. A special focus is placed on the electrolyzer power converter. In particular, the current ripple generated on the side connected to the stack and the efficiency of the converter are studied. A series of tests are carried out to verify the behavior of the system with varying types of thermal conditioning of the hydrides. The results show that the converter used is not optimized for the chosen application, and the thermal conditioning influences the hydrogen adsorption rate and thus the electrolyzer’s behavior. Finally, a technique to operate the system at maximum efficiency is proposed.