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Macro-Encapsulation of Inorganic Phase-Change Materials (PCM) in Metal Capsules

Authors: Stephan Höhlein; Andreas König-Haagen; Dieter Brüggemann;

Macro-Encapsulation of Inorganic Phase-Change Materials (PCM) in Metal Capsules

Abstract

The design of phase-change material (PCM)-based thermal energy storage (TES) systems is challenging since a lot of PCMs have low thermal conductivities and a considerable volume change during phase-change. The low thermal conductivity restricts energy transport due to the increasing thermal resistance of the progressing phase boundary and hence large heat transfer areas or temperature differences are required to achieve sufficient storage power. An additional volume has to be considered in the storage system to compensate for volume change. Macro-encapsulation of the PCM is one method to overcome these drawbacks. When designed as stiff containers with an air cushion, the macro-capsules compensate for volume change of the PCM which facilitates the design of PCM storage systems. The capsule walls provide a large surface for heat transfer and the thermal resistance is reduced due to the limited thickness of the capsules. Although the principles and advantages of macro-encapsulation have been well known for many years, no detailed analysis of the whole encapsulation process has been published yet. Therefore, this research proposes a detailed development strategy for the whole encapsulation process. Various possibilities for corrosion protection, fill and seal strategies and capsule geometries are studied. The proposed workflow is applied for the encapsulation of the salt hydrate magnesiumchloride hexahydrate (MCHH, MgCl 2 · 6 H 2 O) within metal capsules but can also be assigned to other material combinations.

Related Organizations
Keywords

phase-change material, Technology, Microscopy, QC120-168.85, corrosion, T, macro-encapsulation, QH201-278.5, thermal energy storage, waste heat, Engineering (General). Civil engineering (General), Article, TK1-9971, latent heat storage, Descriptive and experimental mechanics, salt hydrate, Electrical engineering. Electronics. Nuclear engineering, TA1-2040

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    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    61
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 1%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 10%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 10%
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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
61
Top 1%
Top 10%
Top 10%
Green
gold