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Corrosion Behaviour of L80 Steel Grade in Geothermal Power Plants in Switzerland

Authors: Ana Vallejo Vitaller; Ueli M. Angst; Bernhard Elsener;

Corrosion Behaviour of L80 Steel Grade in Geothermal Power Plants in Switzerland

Abstract

In Switzerland, deep geothermal energy can give a promising contribution to the future energy scenario. However, the expertise in operational issues of deep geothermal power plants is limited, and technical challenges, such as corrosion, are a determining factor for their reliable and long-term operation. In this work, two representative fluids of optimal geothermal conditions in Switzerland were studied. The corrosiveness of the solutions was assessed using two experimental setups that allow investigating the range of temperatures and pressures that apply to the reservoir and power plant conditions. The corrosion behaviour of API L80 steel was analyzed by means of electrochemical measurements (at 100 and 200 ∘ C ) and of gravimetric tests (at 100 ∘ C ). After the tests, the morphologies and composition of the corrosion products were obtained by scanning electron microscopy (SEM) coupled with energy dispersive X-Ray (EDX) and X-Ray diffraction (XRD). Results show that corrosion rates are significantly high at 100 ∘ C in environments with a chloride concentration of around 600 mg/L and pH around 7. The corrosion products deposited on the metal surface mainly consist of magnetite and/or hematite that might potentially form a protective layer. This study gives a first insight of the potential corrosiveness of geothermal fluids in Switzerland.

Countries
Italy, Switzerland
Keywords

Mining engineering. Metallurgy, autoclave, operational issues, TN1-997, carbon steel, materials degradation, deep geothermal energy; operational issues; materials degradation; carbon steel; autoclave; electrochemistry, electrochemistry, deep geothermal energy

  • BIP!
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    citations
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    6
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Average
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Average
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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
6
Top 10%
Average
Average
Green
gold