This study presents a case study of a novel hybrid solar chimney power plant (HSCPP) design’s performance in the city of Doha, Qatar. The HSCPP construction is similar to the traditional solar chimney power plant (SCPP) but with the addition of water sprinklers installed at the top of the chimney. This allowed the solar chimney (SC) to operate as a cooling tower (CT) during the nighttime and operate as an SC during the daytime, hence providing a continuous 24-h operation. The results showed that the HSCPP produced ~633 MWh of electrical energy per year, compared to ~380 MWh of energy produced by the traditional SCPP. The results also showed that the HSCPP was able to produce 139,000 tons/year of freshwater, compared to 90,000 tons/year produced by the traditional SCPP. The estimated CO2 emission reduction (~600 tons/year) from the HSCPP is twice that of the traditional SCPP (~300 tons/year). The results clearly show that the HSCPP outperformed the traditional SCPP.