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Sustainability
Article . 2022 . Peer-reviewed
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Sustainability
Article . 2022
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Optimized O3/Fe(II) Using Response Surface Methodology for Organic Phosphorus Removal in Tetrakis(hydroxymethyl)phosphonium Sulfate Wastewater

Authors: Yangbin Peng; Hongbin Xu; Yaohua Li; Yuhuan Zhang; Dongge Duan; Mengyue Ren;

Optimized O3/Fe(II) Using Response Surface Methodology for Organic Phosphorus Removal in Tetrakis(hydroxymethyl)phosphonium Sulfate Wastewater

Abstract

Tetrakis(hydroxymethyl)phosphonium sulfate (THPS) wastewater is a kind of industrial wastewater which is difficult to biodegrade. In this work, O3/Fe(II) was used to remove organic phosphorus from THPS wastewater. The operating conditions in this process were optimized using the Box-Behnken response surface method based on single-factor experimentation. A response model of the organic phosphorus removal rate considering the initial pH, reaction time, ozone concentration, and Fe(II) dosage was established. The results showed that the ozone concentration and initial pH had a significant effect on the removal rate of organic phosphorus, and the model fit well (R2 = 0.98). The maximum removal rate of organic phosphorus predicted by this model was 86.04%, while the deviation between the predicted and experimental values was 0.91%. We concluded that the quadratic model was an effective tool for optimizing the removal of organic phosphorus in the THPS wastewater by O3/Fe(II).

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Keywords

Tetrakis(hydroxymethyl)phosphonium sulfate, Environmental effects of industries and plants, TJ807-830, Tetrakis(hydroxymethyl)phosphonium sulfate; ferrous-catalyzed homogenous ozonation; response surface method; Box-Behnken design, ferrous-catalyzed homogenous ozonation, TD194-195, response surface method, Renewable energy sources, Environmental sciences, GE1-350, Box-Behnken design

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    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    4
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 10%
    influence
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    impulse
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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
4
Top 10%
Average
Average
gold