This article proposes an effective evolutionary hybrid optimization method for identifying unknown parameters in photovoltaic (PV) models based on the northern goshawk optimization algorithm (NGO) and pattern search (PS). The chaotic sequence is used to improve the exploration capability of the NGO algorithm technique while evading premature convergence. The suggested hybrid algorithm, chaotic northern goshawk, and pattern search (CNGPS), takes advantage of the chaotic NGO algorithm’s effective global search capability as well as the pattern search method’s powerful local search capability. The effectiveness of the recommended CNGPS algorithm is verified through the use of mathematical test functions, and its results are contrasted with those of a conventional NGO and other effective optimization methods. The CNGPS is then used to extract the PV parameters, and the parameter identification is defined as an objective function to be minimized based on the difference between the estimated and experimental data. The usefulness of the CNGPS for extraction parameters is evaluated using three distinct PV models: SDM, DDM, and TDM. The numerical investigates illustrate that the new algorithm may produce better optimum solutions and outperform previous approaches in the literature. The simulation results display that the novel optimization method achieves the lowest root mean square error and obtains better optima than existing methods in various solar cells.