This study investigated the comparative cultivation of six medicinal plant species (sage, oregano, rosemary, lavender, thyme, and mint) in a dynamic agrivoltaic (AV) system and a neighboring control plot exposed to full sun (referred to as “T”). Specifically, within the dynamic AV system, two distinct plot areas on the ground were identified due to the rotation of the panels: one consistently in the shade of the solar panels (UP), and another alternately in shade and sunlight (BP). The study involved the measurement of solar radiation, air temperature, and infrared leaf temperature during crop growth in these designated plots. Additionally, a weed survey was conducted at harvest time. The findings revealed that solar radiation, air temperature, infrared leaf temperature, and weed coverage were notably lower in the UP plot compared to both the BP and T plots. Furthermore, the yield of essential oils in sage, thyme, mint, and rosemary plants was higher in both the UP and BP plots than in the T plot. Hence, these factors seemingly positively impacted the performance of specific medicinal crops within the dynamic AV system. This information holds significance for producers and processors concerning crop quality.